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Triphenylphosphine oxide can be used: . As a catalyst in Appel-type chlorination reaction of acyclic primary and secondary alcohols.. As a catalyst in stereoselective poly and dibromination of 伪,尾-unsaturated esters and 尾,纬-unsaturated 伪-ketoester compounds.. As a promotor in the diastereoselective synthesis of 伪-ribofuranosides through ribofuranosylation of alcohols with ribofuranosyl iodides.
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